Research Articles Issue 1 · 2024 · pp. 61–70 · Issue page

NEW METHODS OF BENTONITE ACTIVATION AND THEIR EFFICIENCY IN USED MOTOR OILS REGENERATION

KR
SA
DI
AR
VA
AD
1 University of Tirana, Faculty of Natural Sciences, Department of Chemistry, Tirana, Albania
2 University of Tirana, Faculty of Natural Sciences, Department of Chemistry, Tirana, Albania
3 University of Tirana, Faculty of Natural Sciences, Department of Chemistry, Tirana, Albania
4 University of Tirana, Faculty of Natural Sciences, Department of Chemistry, Tirana, Albania
5 Laboratory “Ex Fis Labs”, Pristina, Kosovo
6 University of Tirana, Faculty of Natural Sciences, Department of Chemistry, Tirana, Albania
Received 11 January 2024
Revised -
Accepted 25 February 2024
Available Online 15 March 2024
NEW TECHNIQUES OF BENTONITE ACTIVATION AND THEIR EFFICIENCY IN USED MOTOR OIL (UMO) REGENERATION HAVE BEEB ASSESSED. FOUR METHODS OF RECYCLING USED LUBRICATING OIL (HAVING RUN ABOUT 15 000-20 000 KM) HAVE BEEN EMPLOYED, SUCH AS HEAT/BENTONITE TREATMENT, Na2CO3 /BENTONITE COMBINED WITH MICROWAVE TREATMENT, ACID/BENTONITE COMBINED WITH MICROWAVE TREATMENT, AND NaOH/BENTONITE COMBINED WITH MICROWAVE TREATMENT. VARIOUS TESTS HAVE BEEN CARRIED OUT ON THE RECYCLED USED LUBRICATING OIL, INCLUDING THOSE FOR DENSITY, KINEMATIC VISCOSITY, VISCOSITY INDEX. POUR POINT, COLOR, AND SULFUR CONTENT. THE RESULTS SHOWED THAT ACID - ACTIVATED BENTONITE FOLLOWED BY MICROWAVE TREATMENT WAS MORE EFFICIENT FOR UMO REGENERATION COMPARED TO THE OTHER METHODS.
BENTONITE ACTIVATION MICROWAVE TREATMENT PHYSIC-CHEMICAL
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[1]
S.E. Manahan, Environmental Chemistry. edition S, editor. CRC press: Boca Raton, 2000.
[2]
V. Teneqja," Alternativa teknologjike të përdorimit të bentoniteve të Kosovës për prodhimin e vajit mineral bazë nisur nga riciklimi i vajrave lubrifikues të përdorur", Ph.D. University of Tirana, Albania, 2021.
[3]
J.H. Sherman, N.D. Danielson, R.T. Taylor, J.R. Marsh, and D.T. Esterline," Removal of transition metals from motor oil using ion exchange resins ", Environmental technology , vol. 14, no. 11, pp. 1097-100, 1993.
[4]
M. Sonksen, F. Sittig, and E. Maziarz, editors." Treatment of oily wastes by ultrafiltration/reverse osmosis; a case history", 33rd Indiana Waste Conf Proc;(United States), 1978, pp.
[5]
I. Hamawand, T. Yusaf, and S. Rafat," Recycling of waste engine oils using a new washing agent ", Energies, vol. 6, no. 2, pp. 1023-49, 2013.
[6]
M. Dragne, E. Pop, C.I. Covaliu, E. Matei, and I. Pîşă, editors." Experiments in use of bentonite for energy recovery of used oils", E3S Web of Conferences, 2019, pp. 04009.
[7]
P.F. Luckham, and S. Rossi," The colloidal and rheological properties of bentonite suspensions ", Advances in colloid and interface science, vol. 82, no. 1-3, pp. 43-92, 1999.
[8]
R.H.S. Robertson, Fullers earth: a history of calcium montmonillonite: Volturna Press, 1986. 421 p.
[9]
D.D. Eisenhour, and F.J. Reisch. "Bentonite", in Industrial Minerals & Rocks (7th Edition) , J.E. Kogel, N.C. Trivedi, J.M. Barker, and S.T. Krukowski, Society for Mining, Metallurgy, and Exploration, 2006. pp. 357-68.
[10]
H.H. Murray," Bentonite applications ", Developments in Clay Science, vol. 2, no., pp. 111-30, 2006.
[11]
J. Aguilar, C. Almeida -Naranjo, M.B. Aldás, and V.H. Guerrero, editors." Acid activation of bentonite clay for recycled automotive oil purification", E3S web of conferences, 2020, pp. 03002.
[12]
G. YILMAZ," The effects of temperature on the characteristics of kaolinite and bentonite ", Scientific research and essays, vol. 6, no. 9, pp., 2011.
[13]
Y. Lin, L.K. -J. Cheah, N. Phan -Thien, and B.C. Khoo," Effect of temperature on rheological behavior of kaolinite and bentonite suspensions ", Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 506, no., pp. 1-5, 2016.
[14]
F. Chemat, D. Esveld, M. Poux, and J. Di -Martino," The Role of Selective Heating in the Microwave Activation of Heterogeneous Catmnsis Reactions Using a Continuous Microwave Reactor ", Journal of Microwave Power and Electromagnetic Energy, vol. 33, no. 2, pp. 88-94, 1998.
[15]
O. Zuzana, M. Annamária, D. Silvia, and B. Jaroslav," Effect of thermal treatment on the bentonite properties ", Arhiv za tehnicke nauke, vol. 7, no. 1, pp. 49-56, 2012.
[16]
Y.k. Sarikaya, M.s.e. Önal, B.l. Baran, and T.l. Alemdaro ğlu," The effect of thermal treatment on some of the physicochemical properties of a bentonite ", Clays and Clay Minerals, vol. 48, no. 5, pp. 557 -62, 2000.
[17]
J. Thomas Jr," Particle size effect in m icrowave-enhanced catalysis ", Catalysis Letters, vol. 49, no. 3 - 4, pp. 137-41, 1997.
[18]
B. Toukoniitty, J.-P. Mikkola, D.Y. Murzin, and T. Salmi," Utilization of electromagnetic and acoustic irradiation in enhancing heterogeneous catalytic reactions ", Applied Catalysis A: General , vol. 279, no. 1-2, pp. 1-22, 2005.
[19]
Z. Zhang, Y. Shan, J. Wang, H. Ling, S. Zang, W. Gao, Z. Zhao, and H. Zhang," Investigation on the rapid degradation of congo red catalyzed by activated carbon powder under microwave irradiation ", Journal of Hazardous Materials, vol. 147, no. 1-2, pp. 325-33, 2007.
[20]
K.A. Carrado, and P. Komadel," Acid activation of bentonites and polymer -clay nanocomposites ", Elements, vol. 5, no. 2, pp. 111-6, 2009.
[21]
V. Krupskaya, L. Novikova, E. Tyupina, P. Belousov, O. Dorzhieva, S. Zakusin, K. Kim, F. Roessner, E. Badetti, and A. Brunelli," The influence of acid modification on the structure of montmorillonites and surface properties of bentonites ", Applied Clay Science, vol. 172, no., pp. 1-10, 2019.
[22]
B. Cicel, and I. Novak," DISSOLUTION OF SMECTITES IN HYDROCHLORIC ACID. I. HALF - TIME OF DISSOLUTION AS A MEASURE OF REACTION RATE ", vol., no., pp., 1977.
[23]
H. Bridjanian, and M. Sattarin," Modern recovery methods in used oil re -refining ", Petroleum & Coal, vol. 48, no. 1, pp. 40-3, 2006.
[24]
C. Stan, C. Andreescu, and M. Toma," Some aspects of the regeneration of used motor oil ", Procedia Manufacturing, vol. 22, no., pp. 709-13, 2018.
[25]
J.D. Udonne," A comparative study of recycling of used lubrication oils using distillation, acid and activated charcoal with clay methods ", Journal of Petroleum and Gas Engineering , vol. 2, no. 2, pp. 12-9, 2011.
[26]
H.A. Mekonnen, and A. Ababa," Recycling of used lubricating oil using acid -clay treatment process ", Addis Ababa, vol., no., pp., 2014.
[27]
J. Udonne, and O. Bakare," Recycling of used lubricating oil using three samples of acids and clay as a method of treatment ", International Archive of Applied Sciences and Technology , vol. 4, no. 2, pp. 8, 2013.